Answer
Verified
419.4k+ views
Hint: Diethyl ether can be found if we replace one hydrogen atom of ethanol. This hydrogen atom should be ionizable or replaceable. We also know that alcohol and ether are functional isomers.
Step by step answer:Diethyl ether is formed by the nucleophilic substitution reaction. When ethanol is treated with a second mole of ethanol in the presence of sulphuric acid, diethyl ether is formed by the dehydration process of one of the ethanol molecules.
The reaction occurs as shown below.
In this reaction, the mechanism is followed by the dehydration of ethanol molecules followed by unimolecular nucleophilic substitution reactions. First, the ethanol is treated in the presence of any acid (\[{{\rm{H}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\]) which can give proton. So the water molecule is eliminated from ethanol and carbocation is generated. Now, the second molecule of ethanol will act as a nucleophile and attacks at the electrophilic carbon this process is known as unimolecular nucleophilic substitution. After this step we will get our final product as diethyl ether as shown in the above mechanism.
Therefore, the correct option is option (A).
Note: The above reaction is very sensitive for temperature. If the temperature is \[{\rm{150}}{\;^{\rm{o}}}{\rm{C}}\] or less then only our product will be ether. If the temperature is more than \[{\rm{150}}{\;^{\rm{o}}}{\rm{C}}\] then ethylene will be the product.
Diethyl ether can also be produced by Williamson ether synthesis in which ethanol is treated with any base and then the ethoxide is formed. In this case ethoxide ion acts as a nucleophile and attacks at ethyl chloride. So, the diethyl ether is formed.
Step by step answer:Diethyl ether is formed by the nucleophilic substitution reaction. When ethanol is treated with a second mole of ethanol in the presence of sulphuric acid, diethyl ether is formed by the dehydration process of one of the ethanol molecules.
The reaction occurs as shown below.
In this reaction, the mechanism is followed by the dehydration of ethanol molecules followed by unimolecular nucleophilic substitution reactions. First, the ethanol is treated in the presence of any acid (\[{{\rm{H}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\]) which can give proton. So the water molecule is eliminated from ethanol and carbocation is generated. Now, the second molecule of ethanol will act as a nucleophile and attacks at the electrophilic carbon this process is known as unimolecular nucleophilic substitution. After this step we will get our final product as diethyl ether as shown in the above mechanism.
Therefore, the correct option is option (A).
Note: The above reaction is very sensitive for temperature. If the temperature is \[{\rm{150}}{\;^{\rm{o}}}{\rm{C}}\] or less then only our product will be ether. If the temperature is more than \[{\rm{150}}{\;^{\rm{o}}}{\rm{C}}\] then ethylene will be the product.
Diethyl ether can also be produced by Williamson ether synthesis in which ethanol is treated with any base and then the ethoxide is formed. In this case ethoxide ion acts as a nucleophile and attacks at ethyl chloride. So, the diethyl ether is formed.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
Mark and label the given geoinformation on the outline class 11 social science CBSE
When people say No pun intended what does that mea class 8 english CBSE
Name the states which share their boundary with Indias class 9 social science CBSE
Give an account of the Northern Plains of India class 9 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE
Which are the Top 10 Largest Countries of the World?
One cusec is equal to how many liters class 8 maths CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
The mountain range which stretches from Gujarat in class 10 social science CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths