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How are the following compounds obtained from benzoic acid?
a.) Ethyl benzoate
b.) Benzyl alcohol
c.) Benzene

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Answer
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Hint: . Benzoic acid: It is an organic compound which has a chemical formula of ${ C }_{ 6 }{ H }_{ 5 }{ COOH }$. In this, the carboxyl group is attached to the benzene ring. Benzene can be obtained from benzoic acid in the presence of sodium hydroxide and soda-lime. Ethyl benzoate can be obtained from benzoic acid by using the esterification reaction. Benzyl alcohol can be obtained from benzoic acid by using the hydrogenation reaction.

Complete answer:
A. Ethyl benzoate: When benzoic acid is esterified with ethanol in the presence of an acid catalyst then ethyl benzoate will be produced.
The following reaction will take place:

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B.Benzyl alcohol: When benzoic acid is reduced with lithium aluminum hydride then benzaldehyde will be formed and then again it is reduced then benzyl alcohol will be formed.
The following reaction will take place:

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C. Benzene: When benzoic acid is heated with soda lime, decarboxylation will take place and benzene will be formed.

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Additional Information: Esterification is the reaction in which a carboxylic acid reacts with an alcohol in the presence of concentrated sulphuric acid to form an ester. Esters are basic in natural science and organic materials and regularly have a trademark charming, fruity smell.
Soda Lime: It is a mixture of calcium oxide and sodium hydroxide which is commonly known as soda-lime, (CaO/NaOH). It is used as a drying agent and carbon dioxide absorbent and as a decarboxylating agent.
Decarboxylation (i.e., elimination of ${ CO }_{ 2 }$ ) of sodium salts of carboxylic acids on heating with soda lime (a mixture of NaOH and CaO) gives alkane.


Note: The possibility to make a mistake is that in the formation of benzene from benzoic acid, a decarboxylation reaction (removal of carbon dioxide) occurs, not decarbonylation which is the removal of CO.
Ethyl benzoate can be obtained from benzoic acid by esterification, not acid hydrolysis. Acid hydrolysis is simply the reverse of esterification.
Benzene can be obtained from benzoic acid using soda-lime which is a drying agent. But don’t add too much to the drying agent as it will reduce the yield of the product.