Answer
Verified
434.4k+ views
Hint: Lactic acid contains three carbon atoms. It is obtained from the cyanohydrin of an aldehyde. The number of carbon atoms in the cyanohydrin will be the same as the number of carbon atoms in lactic acid. But the starting aldehyde will have one less carbon atom, as one carbon comes from the cyano group.
Complete step by step answer:
The aldehydes react with hydrogen cyanide to form cyanohydrin.
In the above reaction, ‘R’ represents an alkyl group. The cyanohydrin has an additional carbon atom than aldehyde. This additional carbon atom comes from hydrogen cyanide. The cyano group of hydrogen cyanide is added to carbonyl carbon and the hydrogen atom of hydrogen cyanide is added to carbonyl oxygen. A new carbon-carbon single bond is formed and the carbon-oxygen double bond is converted into a single bond. Aldehyde contains carbonyl groups whereas cyanohydrin contains one hydroxyl group and one cyano group.
The hydrolysis of cyanohydrin gives alpha hydroxy, carboxylic acids.
In the above reaction, the cyano group is hydrolyzed to a carboxylic acid functional group. The number of carbon atoms in the alpha hydroxy carboxylic acid is the same as the number of carbon atoms in the cyanohydrin.
When an alpha hydroxy carboxylic acid is given and it is asked to determine the structure of aldehyde, whose cyanohydrin upon hydrolysis will give the given alpha hydroxy carboxylic acid, then, decrease the number of carbon atoms of the alpha hydroxy carboxylic acid by one to obtain the number of carbon atoms of the aldehyde.
structure of lactic acid is as shown below:
Lactic acid contains 3 carbon atoms. The corresponding aldehyde will have 3-1=2 carbon atoms.
In the given options for aldehydes, the number of carbon atoms in benzaldehyde, formaldehyde, acetaldehyde and propionaldehyde is 7,1, 2, and 3 respectively. Acetaldehyde contains 2 carbon atoms.
Hence, option C) \[{\rm{C}}{{\rm{H}}_3}{\rm{CHO}}\] is the correct answer.
Note:
Since cyano group is added to carbonyl group, cyanohydrin has one excess carbon atom than corresponding aldehyde. Hence, while determining the structure of the starting aldehyde, do not forget to account for additional carbon atoms from the cyano group.
Complete step by step answer:
The aldehydes react with hydrogen cyanide to form cyanohydrin.
In the above reaction, ‘R’ represents an alkyl group. The cyanohydrin has an additional carbon atom than aldehyde. This additional carbon atom comes from hydrogen cyanide. The cyano group of hydrogen cyanide is added to carbonyl carbon and the hydrogen atom of hydrogen cyanide is added to carbonyl oxygen. A new carbon-carbon single bond is formed and the carbon-oxygen double bond is converted into a single bond. Aldehyde contains carbonyl groups whereas cyanohydrin contains one hydroxyl group and one cyano group.
The hydrolysis of cyanohydrin gives alpha hydroxy, carboxylic acids.
In the above reaction, the cyano group is hydrolyzed to a carboxylic acid functional group. The number of carbon atoms in the alpha hydroxy carboxylic acid is the same as the number of carbon atoms in the cyanohydrin.
When an alpha hydroxy carboxylic acid is given and it is asked to determine the structure of aldehyde, whose cyanohydrin upon hydrolysis will give the given alpha hydroxy carboxylic acid, then, decrease the number of carbon atoms of the alpha hydroxy carboxylic acid by one to obtain the number of carbon atoms of the aldehyde.
structure of lactic acid is as shown below:
Lactic acid contains 3 carbon atoms. The corresponding aldehyde will have 3-1=2 carbon atoms.
In the given options for aldehydes, the number of carbon atoms in benzaldehyde, formaldehyde, acetaldehyde and propionaldehyde is 7,1, 2, and 3 respectively. Acetaldehyde contains 2 carbon atoms.
Hence, option C) \[{\rm{C}}{{\rm{H}}_3}{\rm{CHO}}\] is the correct answer.
Note:
Since cyano group is added to carbonyl group, cyanohydrin has one excess carbon atom than corresponding aldehyde. Hence, while determining the structure of the starting aldehyde, do not forget to account for additional carbon atoms from the cyano group.
Recently Updated Pages
Who among the following was the religious guru of class 7 social science CBSE
what is the correct chronological order of the following class 10 social science CBSE
Which of the following was not the actual cause for class 10 social science CBSE
Which of the following statements is not correct A class 10 social science CBSE
Which of the following leaders was not present in the class 10 social science CBSE
Garampani Sanctuary is located at A Diphu Assam B Gangtok class 10 social science CBSE
Trending doubts
A rainbow has circular shape because A The earth is class 11 physics CBSE
Which are the Top 10 Largest Countries of the World?
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
What was the Metternich system and how did it provide class 11 social science CBSE
How do you graph the function fx 4x class 9 maths CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
What is BLO What is the full form of BLO class 8 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE